《Green Synthesis and Catalysis》

作品数：170被引量：54H指数：4
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《Green Synthesis and Catalysis》
主办单位：复旦大学;武汉工程大学
最新期次：2024年4期更多>>
发文主题：METAL-FREEASYMMETRICCATALYSISCATALYZEDCHIRAL更多>>
发文领域：理学化学工程医药卫生环境科学与工程更多>>
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Transition-metal and base-free ether synthesis via alcohol-participated yne-allylic substitution
《Green Synthesis and Catalysis》2024年第4期303-309,共7页Chao Xu Yingkun Luo Shengtong Niu Fan Gong Shouang Lan Benlong Luo Jinggong Liu Shuang Yang Xinqiang Fang 
Financial support was provided by NSFC(Nos.22071242 and 21871260);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);Fujian Natural Science Foundation(Nos.2018J05035 and 2021J01522).
Ethers are among the most important chemicals in organic synthesis,the pharmaceutical industry,agrochemical production,and material science.C–O bond formation via substitution is one of the most widely used strategie...
关键词：Ether synthesis Yne-allylic substitution Transition-metal free Base free ALCOHOL 
Pictet-spengler/transamination cascade reaction of indoles for modular synthesis of marinoquinoline analogues
《Green Synthesis and Catalysis》2024年第4期310-314,共5页Jinjin Chen Pingyu Jiang Xinping Liu Huawen Huang Guojiang Mao Guo-Jun Deng 
Support by the National Natural Science Foundation of China(Nos.22271244 and 22071211);the Hunan Provincial Natural Science Foundation of China(Nos.2023JJ40561 and 2022JJ40359);the Hunan Provincial Health Commission Foundation(B202313020111);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2022C02)is gratefully acknowledged.
The Pictet-Spengler/transamination cascade reaction enables modular synthesis of marinoquinoline analoguesthrough three-component indole ring-expansion/cyclization in the manner of novel N1–C2 cleavage of indoles.Thi...
关键词：Pictet-spengler reaction Indole ring-expansion N1-C2 cleavage INDOLE Marinoquinoline analogues 
Photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines
《Green Synthesis and Catalysis》2024年第4期315-318,共4页Jingjing Wang Feng Li Kai Liu Chong Li Sheng Cao Yuxiang Wu Yongjun Yuan Fei Teng Teng Wang Yao Zhou 
supported by the National Natural Science Foundation of China(Nos.21402116 and 21502111);the Key Scientific and Technological Project of Henan Province(No.222102310607);the Key Science Research of Education Committee in Henan Province(Nos.21A150044 and 22A150051);the Shandong Provincial Natural Science Foundation(Nos.ZR2023QH502 and ZR2023QB172);the Doctoral Research Foundation of Zaozhuang University.
We first describe a photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines.The desired products were generated in moderate to good yields with wide substrate scope under mild reactio...
关键词：PHOTOINDUCED DECATUNGSTATE C-H functionalization CYCLOALKANES Cyclic aldimines 
Visible-light-induced radical-cascade alkylation/cyclization of N-methacryloyl-2-phenylbenzimidazole:Access to benzoimidazo[2,1-a]isoquinolin-6(5H)-ones
《Green Synthesis and Catalysis》2024年第4期319-323,共5页Yanhong Wang Xinlei Zhou Tao Zhang Xinxin Ren Wei Xu Bin Wang Weiwei Jin Yu Xia Chenjiang Liu Yonghong Zhang 
supported by the Natural Science Foundation of Xinjiang Uyghur Autonomous Region(Nos.2022E01042,2022TSYCCX0024,and 2021D01E10);the NSFC(Nos.21861036,21961037 and 21762041).
A metal-free visible-light-induced synthesis of aza-polycyclic aromatic hydrocarbons via cascade alkylation/cyclization of N-methacryloyl-2-phenylbenzimidazole was developed.The reaction was carried out with inactive ...
关键词：Visible light catalysis PHENANTHRENEQUINONE Benzimidazole[2 1-a]isoquinoline-6(5H)-ones Radical cascade reactions Hydrogen atom transfer(HAT) 
Solvent-controlled stereodivergent synthesis of E-and Z-enamines via metal-free formal C(sp^(2))-H amination ofα-substituted styrenes
《Green Synthesis and Catalysis》2024年第4期324-328,共5页Dangui Wang Jinbei Yao Wentao Zhang Shuyue Zhang Huaibin Yu Laihu Peng Weijun Yao Zhifeng Dai Guojiao Wu Fangrui Zhong 
supported by the National Natural Science Foundation of China(No.22001085);Shandong Provincial Natural Science Foundation(No.ZR2021QB148);Fundamental Research Funds for the Central Universities(No.HUST:2023JCYJ001);Research Institute of Zhejiang Sci-Tech University in Longgang(No.LGYJY2021013)for financial support。
C(sp^(2))-H amination represents an attractive approach for the synthesis of enamines,which is intrinsically associated with the challenge of controlling of stereochemistry and primarily relying on transition-metal ca...
关键词：ENAMINES Stereodivergent synthesis METAL-FREE Hypervalent iodine C(sp^(2))-H aminatio 
Carbonylative transformation of aryl halides and strong bonds via cheap metal catalysts and sustainable technologies
《Green Synthesis and Catalysis》2024年第4期211-269,共59页Maolin Yang Yukun Liu Xin Qi Yanhua Zhao Xiao-Feng Wu 
financial support from the National Key R&D Program of China(No.2023YFA1507500);We also appreciate the general support provided by Prof.Armin Borner at Leibniz-Institute for Catalysis.
The development of catalytic carbonylation reactions has increased considerably.Although many reviews/chapters/books on carbonylation reactions have been published,summaries on cheap metal-catalyzed catalytic carbonyl...
关键词：CARBONYLATION Aryl halides(C(sp^(2))-X) Strong bonds C-Y(Y=O N H) Cheap metal Photochemical and electrochemical systems Green and sustainable chemistry 
Recent advances in(4+3)cycloaddition of allenes
《Green Synthesis and Catalysis》2024年第4期270-276,共7页Yanyan Que Wenli Lei Yin Fang Shuzhong He Yang Chen 
financial support from the supported by National Natural Science Foundation of China(Nos.22061008 and 22361008);the State Key Laboratory of Natural and Biomimetic Drugs(No.K202223);the Science and Technology Foundation of Guizhou Province(Nos.ZK[2021]-039 and[2023]-097);the State Key Laboratory of Functions and Applications of Medicinal Plants,Guizhou Medical University(No.FAMP202102K).
Allenes are a class of unsaturated compounds containing a propadiene structural moiety,exhibiting essential physiological,pharmacological,and various reactivities.Their(4+3)cycloaddition reaction has become an effecti...
关键词：ALLENES (4+3)Cycloaddition Asymmetric catalysis Seven-membered heterocycles 
Visible-light induced photocatalyst-free difluoromethylation of quinoxalinones with difluorosulfones
《Green Synthesis and Catalysis》2024年第4期277-281,共5页Linlin Shi Tiantian Li Wenjing Zhang Weinan Hu Xinju Zhu Yixin Lu Guang-Jian Mei 
Financial support from the National Natural Science Foundation of China(Nos.22101267,U1904212,U2004191 and 21803059)is gratefully appreciated.
Visible-light induced direct C–H difluoromethylation of quinoxalinones with 2-((difluoromethyl)sulfonyl)benzo[d]thiazole has been developed for the first time.A broad range of quinoxalinones were well tolerated and r...
关键词：Quinoxalinones DIFLUOROMETHYLATION Visible-light induced Photocatalyst-free Difluorosulfones 
Highly enantio-stereoselective Ni-catalyzed reductive cyclization to cyclopentanes with chiral quaternary centres of trisubstituted allylic siloxanes
《Green Synthesis and Catalysis》2024年第4期282-289,共8页Wanjun Chen Xinlong Yan Lin Fan Xu Guo Jian Yang Yiming Chen Shaofang Zhou Guodu Liu 
financial support provided by the National Natural Science Foundation of China(No.22061032);Natural Science Foundation of Inner Mongolia(Nos.2020MS02022,and 2022QN02005);Science and Technology Program of Inner Mongolia(No.2020GG0134);Opening-fund from State Key Laboratory of Bio-organic and Natural Products Chemistry of SIOC(No.21300-5206002);“JUN-MA”Highlevel Talents Program of Inner Mongolia University(No.21300-5185121);“Grassland Talents”Program of Inner Mongolia(No.12000-12102414);High-level Recruit Program of Inner Mongolia(No.12000-13000603);Key Project at Central Government Level:the ability establishment of sustainable use for valuable Chinese medicine resources(No.2060302)is sincerely acknowledged。
The construction of chiral quaternary carbon stereocenters is a significant challenge in asymmetric synthesis.Catalytic synthesis of these structures with trisubstituted allylic alcohols is highly important. However, ...
关键词：All carbon 1 6-alkynone Ni-catalyzed reductive cyclization Stereoselective asymmetric catalysis Cyclopentane with chiral allylic quaternary stereocenter P-Chiral monophosphine ligand 
Development of a more efficient catalyst for the redox-neutral organocatalytic mitsunobu reaction by DFT-guided catalyst design
《Green Synthesis and Catalysis》2024年第4期290-296,共7页Dingguo Song Changjun Zhang Yuqi Cheng Linlin Chen Jie Lin Changdi Zheng Ting Liu Yuxin Ding Fei Ling Weihui Zhong 
financially supported by the National Natural Science Foundation of China(Nos.22078298,21978271 and 22178315);Natural Science Foundation of Zhejiang Province(No.LY21B020007);China Postdoctoral Science Foundation(No.2022M712824);Key Research and Development Program of Zhejiang Province(No.2023C03117).
The study of a Mitsunobu reaction is an important topic.Denton and co-workers first reported a novel(2-hydroxybenzyl)diphenylphosphine oxide for realizing the catalytic Mitsunobu reaction via a five-membered phosphoni...
关键词：Phosphine oxide Mitsunobu reaction Late-sFtage diversification Drug discovery process 
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