funding supports from Guizhou Provincial Basic Research Program(Natural Science)(No.QianKeHeJiChu-ZK[2024]YiBan086);the starting grant of Guizhou University[(2023)5].
An electrocatalytic multicomponent cascade cross-coupling for the synthesis of chalcogenosulfonates has been established.This approach does not require the use of transition metals,acids,and external oxidants.The gent...
supported by the National Natural Science Foundation of China(21801152 and 21572110);the Youth Innovation Science and Technology Plan of Colleges and Universities in Shandong Province(2021KJ076).
An efficient electrochemical approach has been developed for the construction of 3-sulfanylquinoline derivatives by treating phenylethynylbenzoxazinanones with disulfides in an undivided cell.The protocol provided a c...
the Scientific Research Fund of Hunan Provincial Education Department(21B0262 and 22B1094);the Natural Science Foundation of Hunan Province(2022JJ40857);the Hunan Provincial Innovation Foundation For Postgraduate(CX20230757)forfinancial support.
An alkyl radical initiated cyclization/tandem reaction of alkyl bromides and alkyl electrophiles by using potassium metabisulphite(K_(2)S_(2)O_(5))as a connector is developed for the synthesis of various lactam-substi...
the National Natural Science Foundation of China(Nos.21772138 and 21672157);the Natural Science Foundation of Jiangsu Province(BK20221356);PAPD。
A series of 3-acyl-substituted isoindolinone derivatives were synthesized in a one-pot manner via the reaction of o-bromobenzaldehydes,isocyanides,and carboxylic acids in the presence of palladium catalyst and base. T...
supported by the National Natural Science Foundation of China(21871094);the Guangxi Key Laboratory of Zhuang and Yao Ethnic Medicine[(2014)No.32];We also thank the support of the Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation(No.2021CL04).
Here is an operable and rare strategy for copper-initiated radical dearomative 2,5-alkylarylation of furan. By means of this strategy, we realized the dearomatization of furans to construct spirooxindoles with good yi...
supports from theNational Natural Science Foundation of China(22175194);Shanghai Scientific and Technological Innovation Project(20QA1411600,20ZR1469200);Hundred Talents Program from Shanghai Institute of Organic Chemistry(Y121078).
Difluoroboronβ-diketonate(BF2bdk)compounds represent an important class of luminescent materials,whereas their synthesis requires multiple steps,which restrict their application in diverse fields.Here we report a cas...
We are grateful for financial support from the National Natural Science Foundation of China(Nos.21871112 and 21971090);the Science and Technology of Xuzhou(KC21022)。
Molecular scaffolds endowed with all-carbon quaternary stereocenter are ubiquitous in natural products and significant bioactive molecules.However,efficient construction of this type of structure units is full of chal...
Financial support from the National Natural Science Founda-tion of China(Nos.21971096,21772079,&21672088);the Natural Science Foundation of Gansu Province(No.18JR4RA003)is acknowledged.
Cedrane sesquiterpenes possess common tricyclo[5.3.1.0^(1,5)]undecane core structure.The varied oxa-five-membered ring decorating their core structure to form 8-oxa-tetracyclo[7.2.2.0^(1,5).0^(6,13)]tridecane framewor...
This work was supported by grants from the Research Grants Council of The Hong Kong Special Administration Region(Nos.14305017,14305018 and 14305918)and Direct Grant from Fac-ulty of Science,CUHK.
Summary of main observation and conclusion Ir-catalyzed cascade dehydrogenative CH/BH and BH/OH cross-coupling of carboranyl carboxylic acid with readily available benzolc acid has been achieved,leading to the facile ...
Intramolecular hydride transfer has long been recognized as a powerful method to gen-erate new stereogenic centers induced by the existing stereogenic center(s).Synthetical-ly significant selectivities are usually obt...