云南高校图书馆联盟文献共享服务平台- ENANTIOSELECTIVE

ENANTIOSELECTIVE: 作品数：269被引量：197H指数：5; 导出分析报告; 相关领域：理学更多>>; 相关作者：夏飞刘秀艳皮超张俊良曾苏更多>>; 相关机构：华东师范大学郑州大学南开大学中国科学技术大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>

Enantioselective Borylative Functionalization of Internal Alkenes:A Platform for Constructing Vicinal Stereocenters: 《Chinese Journal of Chemistry》2024年第24期3588-3604,共17页Yu-Shen Zhu Jia-Xin Li Hao-Tian Zhao Bo Su; National Natural Science Foundation of China(22271161,22188101);the Tianjin Science Fund for Distinguished Young Scholars(23JCJQJC00180);the Fundamental Research Funds for the Central Universities(63233165,63243134);Nankai University,for financial support.; Vicinal stereogenic centers are ubiquitous structural scaffolds in both natural products and synthetic compounds,yet their enantioselective construction remains a significant challenge in organic synthesis.Organoboron...; 关键词：Borylative functionalization ORGANOBORON Vicinal stereogenic centers Transition metal catalysis Asymmetric synthesis

Catalytic Enantioselective Functionalization of Maleimides:An Update: 《Chinese Journal of Chemistry》2024年第24期3605-3622,共18页Muriel Amatore Damien Bonne Thierry Constantieux Jean Rodriguez; Maleimide derivatives are well-established reactive intermediates also found in natural products,synthetic pharmaceuticals and functional polymers.Their specific reactivity found widespread applications in the field o...; 关键词：MALEIMIDES Enantioselective catalysis ADDITIONS CYCLOADDITIONS HETEROCYCLES Domino reactions

Reduction of Tertiary Carbon Radicals via Asymmetric Hydrogen Atom Transfer(AHAT): 《Chinese Journal of Chemistry》2024年第24期3414-3428,共15页Xue Han Chuan He; the National Natural Science Foundation of China(22122102,22271134);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);Guangdong Peari River Talent Program(2019QN01Y628);ShenzhenScience and Technology Innovation Committee(RCJC20221008092723013,JCYJ20230807093104009).; In the past two decades,the development of asymmetric radical reactions has achieved tremendous progress,which has emerged as a powerful tool for the synthesis of chiral molecules in synthetic chemistry.Among the dive...; 关键词：AHAT Radical reactions Asymmetric synthesis Enantioselective radical reactions Hydrogen atom transfer CHIRALITY REDUCTION Synthetic methods

Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes: 《Chinese Journal of Chemistry》2024年第20期2466-2470,共5页Lujia Zhou Longling Ma Bing Xu Zhan-Ming Zhang Junliang Zhang; support of the National Key R&D Program of China(No.2021YFF0701600),NSFC(No.22031004);the Shanghai Municipal Education Commission(No.20212308);China Postdoctoral Science Foundation(No.2022M713667)and STCSM(No.23ZR1445600).; A highly enantioselective palladium-catalyzed intramolecular Heck reaction of unactivated alkenes is developed,which provides a powerful route to access a broad range of chiral 3,3-disubstituted-2,3-dihydrobenzofurans...; 关键词：PALLADIUM HECK 2 3-Dihydrobenzofuran Asymmetric catalysis Quaternary stereocenter ENANTIOSELECTIVE P ligands ALKENES

Construction of Acyclic Quaternary Carbon Stereocenters via Enantioselective Nickel Catalysis: 《Chinese Journal of Chemistry》2024年第20期2485-2498,共14页Jian Song Xuening Li Jinguo Long Hua Yang Xianjie Fang; National Natural Science Foundation of China(Nos.22278265,U22B20137);Zhejiang Provincial Natural Science Foundation of China(No.LR24B020002);the start-up funding from Hangzhou Normal University(No.4095C50222204165);support.J.S.thanks the Natural Science Foundation of Hunan Province(2024JJ6485);support.J.L.thanks the National Natural Science Foundation of China(22302063);China Postdoctoral Science Foundation(2022M721086);the Natural Science Foundation of Hunan Province(2023JJ40124)for financial support.; The construction of acyclic quaternary carbon stereocenters,which are ubiquitous in many bioactive compounds,pharmaceuticals and natural products,has been a long persuit in synthetic organic chemistry.Among numerous m...; 关键词：Nickel catalysis ENANTIOSELECTIVITY ALKENES ACYCLIC Quaternary carbon stereocenters Asymmetric catalysis CROSS-COUPLING Chirality

Chiral Isothiourea-Catalyzed Acylative Dynamic Kinetic Resolution of 3-Hydroxyphthalides for Enantioselective Synthesis of Phthalidyl Esters: 《Chinese Journal of Chemistry》2024年第19期2341-2345,共5页Zeyang Hao Wei Lin Zi-Qi Yuan Wei Zhang Xin Li; support from the National Natural Science Foundation of China(Grant Nos.22371219,22193011,21971120,21933008 and 22101191);National Science&Technology Fundamental Resource Investigation Program of China(No.2018FY201200);the Fundamental Research Funds for the Central Universities.W.Z.is grateful for the financial support from the program of China Scholarship Council(No.202206240054).; Comprehensive Summary Phthalides serve as core structures pervasive in a wide array of natural products and drug molecules,which display a diverse array of biological activities.We report herein a highly efficient dyn...; 关键词：Asymmetric catalysis Phthalidyl ester Dynamic kinetic resolution Chiral isothiourea ACYLATION Methodology and reactions Syntheticmethods

De novo Synthesis of Chiral 3,4-Dihydroquinazolines via One-Pot Enantioselective Ugi-Azide/Cyclization Sequences: 《Chinese Journal of Chemistry》2024年第18期2140-2146,共7页Zu-Kui Xie Jun-Jun Ding Yi-Ming Ou Jun-Xiu Shi Meng-Lan Shen Chuan-Zhi Yao Hua-Jie Jiang Jie Yu; financial support from NSFC(Grant No.92156022);Anhui Provincial Natural Science Funds(Grant Nos.2308085MB43,2308085QB44);Shennong Scholar Program of Anhui Agricultural University,and National Undergraduate Training Program for Innovation and Entrepreneurship.; Background and Originality Content,3,4-Dihydroquinazoline frameworks have frequently been encountered in natural products and bioactive molecules.In the past decades,these key structures prompted the development of cr...; 关键词：Anionic stereogenic-at-cobalt(ll)complex De novo synthesis post-Ugi transformation One-pot sequence Asymmetric synthesis Multicomponentreactions

Ni-Catalyzed Enantioselective Difunctionalization of Alkynes to Azepine Derivatives Bearing a Quaternary Center and an Unprotected Imine: 《Chinese Journal of Chemistry》2024年第8期873-878,共6页Jian Long Zhiwu Lu Xiao-Lin Li Peng Xue Wen-Bo Liu; supported by NSFC(22222111,21971198,and 22371215);National Key R&D Program of China(2022YFA1502902);Large-scale Instrument and Equipment Sharing Foundation of Wuhan University.Dr.Zhiwu Lu thanks China Postdoctoral Science Foundation(2022M712458)for the financial support.; Comprehensive Summary,The azepine ring is a prominent structural scaffold in biologically significant molecules. In this study, we present a Ni(II)-catalyzed asymmetric difunctionalization of alkynes, involving interm...; 关键词：Nickel Asymmetric catalysis N-HETEROCYCLES Alkyne functionalization Quaternary centers

Enantioselective Synthesis of Benzimidazole Atropisomers Featuring a N-N Axis: 《Chinese Journal of Chemistry》2024年第7期711-718,共8页Fang-Bei Ge Qi-Kun Yin Chuan-Jun Lu Xuan Xuan Jia Feng Ren-Rong Liu; supported by Taishan Scholar Youth Expert Program in Shandong Province (tsqn201909096);National Natural Science Foundation of China (22371152);Shandong Provincial Natural Science Foundation Project (ZR2023JQ006,ZR2022MB021);the startup fund from Qingdao University.; Atroposelective synthesis of N-N atropisomers is an emerging area but remains underexplored;in particular,the synthesis of N-N benzimidazole atropisomers is still unprecedented.Herein,the first enantioselective synthe...; 关键词：Asymmetric synthesis ATROPISOMERISM PALLADIUM BENZIMIDAZOLE ANTITUMOR

Enantioselective and Enantioconvergent Iron-Catalyzed C(sp^(3))-H Aminations to Chiral 2-Imidazolidinones被引量：1: 《Chinese Journal of Chemistry》2023年第17期2065-2070,共6页Tianjiao Cui Chen-Xi Ye Jordan Thelemann Daniel Jenisch Eric Meggers; the European Research Council(ERC)under the European Union's Horizon 2020 research and innovation programme(grant agreement No.883212).; Comprehensive Summary Enantioselective or enantioconvergent iron-catalyzed ring-closing C(sp^(3))-H aminations of N-aroyloxyurea through intermediate iron nitrene species provide chiral 2-imidazolidinones in up to 99%...; 关键词：Iron Asymmetric catalysis C-H activation AMINATION NITRENES HETEROCYCLES

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