ENYNES

作品数:33被引量:23H指数:2
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相关领域:理学更多>>
相关作者:柳凌艳黄开盟李靖更多>>
相关机构:南开大学北京大学更多>>
相关期刊:《Science China Chemistry》《Science Bulletin》《Green Synthesis and Catalysis》《Chinese Journal of Catalysis》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划湖南省自然科学基金中央级公益性科研院所基本科研业务费专项更多>>
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Redox-Neutral Nickel-Catalyzed Selective Hydroalkynylation of Internal Alkyne and Its Application in Anticancer Agent Discovery
《Chinese Journal of Chemistry》2024年第24期3317-3323,共7页Weiming Chen Teng Liu Shuqing Li Guangyu Li Gaorong Wu Youjia Gao Zhilin Xu Yitao Wu Xiaopeng Peng Jiuzhong Huang 
supported by the National Natural Science Foundation of China(22361003,82260676);Talent Project of Jiangxi Province(jxsq2019101065);the Jiangxi Provincial Natural Science Foundation(20224BAB216005,20232BAB216131);the Science and Technology Projects of Ganzhou(202101094462,2023PNS26854);The Start-up Fund of Gannan Medical University.
Herein,an unprecedented nickel-catalyzed regioselective hydroalkynylation of unsymmetrical internal alkynes was realized with steric hindered resistance selectivity via the cyano-directing group strategy.Significantly...
关键词:Directing group strategy Hydroalkynylation 1 3-Enynes Dihydroindeno[2 1-c]pyrazole Anti-tumor candidate 
Copper-catalyzed photoredox 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN:Facile access toα-amido allenyl nitriles
《Chinese Chemical Letters》2024年第11期344-348,共5页Liangfeng Yang Liang Zeng Yanping Zhu Qiuan Wang Jinheng Li 
the National Natural Science Foundation of China(No.22271245)for the financial support;the Yantai“Double Hundred Plan”;the Talent Induction Program for Youth Innovation Teams in Colleges and Universities of Shan-dong Province。
A new 1,4-amidocyanation of 1,3-enynes with N-amidopyridin-1-ium salts and TMSCN using a copper and photoredox synergetic catalysis for producingα-amido allenyl nitriles is developed.Employing N-amidopyridin-1-ium sa...
关键词:Copper Photoredox catalysis Amidocyanation N-(Sulfonamido)pyridin-1-ium salts 1 3-Enynes α-Sulfonamido allenyl nitriles 
Copper/Photoredox-Catalyzed Regioselective 1,4-Addition to 1,3-Enynes: A Convenient Access to Perfluoroalkylated Allenes
《Chinese Journal of Chemistry》2024年第17期2023-2028,共6页Ya Chen Quanyuan Wang Keyi Peng Lilei Cheng Ziyi She Guo-Jun Deng 
supported by the National Natural Science Foundation of China(Nos.22301256 and 22271244);the Hunan Provincial Natural Science Foundation of China(2023JJ40618);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2022c02);the Hunan Provincial Innovation Foundation for Postgraduate(CX20230644,XDCX2023Y162)
A general and broadly applicable copper and photoredox dual-catalyzed multicomponent 1,4-perfluoroalkylcyanation of 1,3-enynes has been developed.This protocol enjoys success with high regioselectivity,mild reaction c...
关键词:Fluorinated allenes 1 3-Enynes PHOTOREDOX FLUOROALKYLATION Multicomponent reactions Difunctionalization Radicals Regioselectivity 
Acylfluorination of enynes via phosphine and silver catalysis
《Chinese Chemical Letters》2024年第8期260-264,共5页Yu Mao Yilin Liu Xiaochen Wang Shengyang Ni Yi Pan Yi Wang 
support from the National Natural Science Foundation of China(Nos.21971107,22071101,22271147).
This work describes intermolecular acylfluorination of gem-difluoroenynes using acyl fluorides as both acyl source and fluorine source.Trifluoromethyl-substituted allenones or furans could be selectively achieved via ...
关键词:Phosphine catalysis Silver catalysis Difunctionalization Allenone FURAN TRIFLUOROMETHYL 
Nickel-catalyzed carbonylative four-component 1,4-dicarbofunctionalization of 1,3-enynes
《Science China Chemistry》2024年第6期2029-2038,共10页Yan Zhao Qi-Chao Shan Hong Xin Pin Gao Xu Yang Xin-Hua Duan Li-Na Guo 
supported by the National Natural Science Foundation of China(22171220,21971201);the Fundamental Research Funds of the Central Universities(xtr072022003)。
An efficient Ni-catalyzed four-component 1,4-carbocarbonylation of 1,3-enynes with activated alkyl halides and arylboronic acids under atmospheric pressure of CO is presented.By tuning the electronic and steric effect...
关键词:Ni catalysis four-component 1 4-carbocarbonylation 1 3-enynes 
Cu-catalyzed regioselective diborylation of 1,3-enynes for the efficient synthesis of 1,4-diborylated allenes
《Chinese Chemical Letters》2024年第5期141-144,共4页Wujun Jian Mong-Feng Chiou Yajun Li Hongli Bao Song Yang 
supported by the National Natural Science Foundation of China(NSFC,Nos.22001251,21922112,and 22225107);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);National Key R&D Program of China(No.2017YFA0700103);the Guizhou Provincial S&T Project(No.2018[4007]).
Borylation of 1,3-enynes with bis(boronate)compounds often ends up with the formation of hydroborylated products,leaving the diborylation of 1,3-enynes for the formation of 1,4-diborylated allenes to be challenging.He...
关键词:Copper catalysis REGIOSELECTIVE 1 3-Enynes BORYLATION ALLENES 
Ni-catalyzed highly regio- and stereo-selective diborylative cyclization of 1,6-enynes with diboron reagent
《Science China Chemistry》2024年第3期981-989,共9页Qitao Guan Zhen Shen Yiqiang Tian Genping Huang Chun Zhang 
supported by Tianjin University(B22021-010);the State Key Laboratory of Elemento-Organic Chemistry;the National Natural Science Foundation of China(22371203,22073066,21503143,21975179)。
The Ni-catalyzed highly selective diborylative cyclization of 1,6-enynes with diboron reagent has been developed. When pinB-Bdan was used, multiple types of boron-containing functional groups could be installed into o...
关键词:NICKEL-CATALYZED ORGANOBORON CYCLIZATION regioselectivity ENANTIOSELECTIVITY 
Catalytic asymmetric synthesis of 1,4-enynes
《Chinese Chemical Letters》2023年第8期18-27,共10页Han-Yu Lu Zhi-Tao He 
We are grateful for the financial support from the National Natural Science Foundation of China(NSFC,No.22071262);the Science and Technology Commission of Shanghai Municipality(No.22ZR1475200);Shanghai Rising-Star program(No.20QA1411300).
1,4-Enyne units are ubiquitous skeletons in biologically active molecules and natural products.Especially,they represent versatile building blocks for abundant downstream derivatizations via controllable modifications...
关键词:1 4-Enynes Catalytic reaction Asymmetric synthesis 
Ni-catalyzed regiodivergent hydrophosphorylation of enynes
《Chinese Chemical Letters》2023年第6期301-305,共5页Sa-Na Yang Shao-Han Sun Chang-Hui Liu Xiang-Ting Min Boshun Wan Ding-Wei Ji Qing-An Chen 
Financial support from Dalian Outstanding Young Scientific Talent(No.2020RJ05);the National Natural Science Foundation of China(Nos.22071239,21971234)。
A regiodivergent hydrophosphorylation of enynes with phosphites has been developed using earthabundant nickel catalyst.The manipulation of regioselectivity can be achieved by regulating the insertion order of alkyne b...
关键词:Regiodivergent HYDROPHOSPHORYLATION Nickel catalysis ENYNES 
Pd-catalyzed functionalization of 1,3-enynes via alkylene-π-allylpalladium intermediates
《Green Synthesis and Catalysis》2023年第2期124-134,共11页Long Li Shan Wang Ajay Jakhar Zhihui Shao 
supported by the National Natural Science Foundation of China(Nos.22171240 and 21861042);the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT17R94);China Postdoctoral Science Foundation(No.2020M712707)。
In recent years,the concept of transition metal-catalyzed functionalization of unsaturated hydrocarbons has emerged as a promising strategy for developing new and valuable reactions,and has attracted considerable atte...
关键词:PALLADIUM-CATALYZED 1 3-Enynes Alkylidene-π-allylpalladium intermediates 
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