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CATALYSIS: 作品数：1542被引量：2818H指数：17; 导出分析报告; 相关领域：理学更多>>; 相关作者：吴骊珠孟庆元佟振合张强刘娜更多>>; 相关机构：中国科学院清华大学华东理工大学中国科学院大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金北京市自然科学基金更多>>

Catalytic Selective Functionalization of Poly(organoborons): 《Chinese Journal of Chemistry》2024年第24期3484-3498,共15页Jia-Hui Zhao Ang Chen Xi-Zhang Zou Chong-Lei Ji Huang-Di Feng De-Wei Gao; We gratefully acknowledge NSFC(Grant No.22101177);the Science and Technology Commission of Shanghai Municipality(Grant Nos.23YF1426700 and 21ZR1442000);start-up funding of ShanghaiTech University for their generous financial support.; Organoborons are commonly used building blocks for rapidly increasing molecular complexity.Although significant progress has been made in the selective functionalization of mono-organoborons,the site-selective functio...; 关键词：Poly(organoborons) Selective functionalization Asymmetric catalysis CROSS-COUPLING PHOTOCATALYSIS

Repurposing Naturally Occurring Enzymes Using Visible Light: 《Chinese Journal of Chemistry》2024年第24期3553-3558,共6页Yuanyuan Xu Fulu Liu Beibei Zhao Xiaoqiang Huang; the National Natural Science Foundation of China(22277053 to X.H.;223B2703 to Y.X.);the National Key Research and Development Program of China(2022YFA0913000 to X.H.);the Natural Science Foundation of Jiangsu Province(BK20220760 to X.H.);the Fundamental Research Funds for the Central Universities(0205/14380346 to X.H.);the Excellent Research Program of Nanjing University(ZYJH004 to X.H.).; Enzymes are natural treasure troves that hold multiple superiority.Enzymatic catalysis has become a powerful tool for asymmetric synthesis,though it is typically limited to a relatively narrow range of reaction types....; 关键词：Photoenzymatic catalysis New-to-nature reactivity Asymmetric catalysis Enzyme catalysis Photoredox catalysis

Borane-Catalyzed Asymmetric Reduction of 2-Alkylpyridines: 《Chinese Journal of Chemistry》2024年第23期3088-3092,共5页Heng Luo Zhao-Ying Yang Ming Zhang Xiao-Chen Wang; the National Natural Science Foundation of China(Nos.22371141,22221002);National Key R&D Program of China(No.2021YFA1500200);Natural Science Foundation of Tianjin(No.20JCJQJC00030);Haihe Laboratory of Sustainable Chemical Transformations(No.ZYT202101);Frontiers Science Center for New Organic Matter at Nankai University(No.63181206);Tencent Foundation for financial support.; Herein,a method for the enantioselective reduction of unprotected 2-alkylpyridines is reported for the first time.By using pinacolborane and an amide as reducing agents,a large number of 2-alkylpiperidines were synthe...; 关键词：ORGANOBORON Asymmetric Catalysis PYRIDINE PIPERIDINE Heterocycles Homogeneous catalysis Reduction CHIRALITY

Earth-Abundant Nickel-Catalyzed Asymmetric Hydrogenation: 《Chinese Journal of Chemistry》2024年第23期3135-3156,共22页Peng Wang Zhao-Lin He Zi-Fei Xia Jun Wei Xiu-Qin Dong; financial support from National Natural Science Foundation of China(22071187,22271226);Natural Science Foundation of Hubei Province(2021CFA069);National Youth Talent Support Program。; Transition metal-catalyzed asymmetric hydrogenation is an efficient and direct synthetic method to access chiral compounds,which features simplicity,easy working-up process,and high atomic economy.It typically relies ...; 关键词：Transition metal Nickel HYDROGENATION ENANTIOSELECTIVITY Asymmetric catalysis Earth-abundant metal

Amide-Based Morita–Baylis–Hillman Carbonates for Phosphine-Catalyzed Asymmetric(4+2)Annulation: 《Chinese Journal of Chemistry》2024年第24期3269-3277,共9页Min Liu Qihuan Han Lan Wang Xi Chen Xue Zhang Hongchao Guo; supported by the National Natural Science Foundation of China(Nos.21871293,22071264).; Chiral phosphine-catalyzed asymmetric(4+2)annulation of the amide-based Morita–Baylis–Hillman(MBH)carbonates withβ,γ-unsaturated butenolides has been developed to give enantiomer-enriched bicyclicδ-lactamγ-butyr...; 关键词：Asymmetric catalysis Asymmetric synthesis Phosphine catalysis Organocatalysis Cycloaddition ANNULATION AMIDE MBH carbonate LACTAM Piperidinone Heterocycle

Functionalization of Boranes through Thiol/Oxygen Catalysis: 《Chinese Journal of Chemistry》2024年第22期2804-2810,共7页Hongyi Tao Hairong Lyu; supported by research start-up fund(Project No.4933621)from the Chinese University of Hong Kong.Mr.Weixuan Sun is thanked for checking the experimental procedure。; A greener and more convenient alternative to traditional methods for the generation of thiyl radical as hydrogen atom transfer(HAT)catalyst is developed,using molecular oxygen to oxidize thiol without the need for che...; 关键词：BORANES Thiyl radical Oxygen Borane difunctionalization Synthetic methods Green chemistry

Recent Advances of Amorphous Nanomaterials:Synthesis and Applications: 《Chinese Journal of Chemistry》2024年第22期2853-2876,共24页Lidong Li Hewei Zhao Xiaotian Wang Lin Guo; supported by the National Natural Science Foundation of China(Nos.51532001,52272181 and 51872016).; Amorphous nanomaterials are metastable nanomaterials which only have short-range order within a few neighboring atoms,based on the local chemical bondings.Different from crystalline materials,the amorphous nanomateria...; 关键词：AMORPHOUS NANOMATERIALS CATALYSIS Energy storage MECHANICS Amorphou structure Applications Synthesis design

Metal-Decorated Porous Organic Polymers:Bridged the Gap between Organic and Inorganic Scaffolds: 《Chinese Journal of Chemistry》2024年第22期2902-2934,共33页Zhu Gao Yufei Liu Shaofei Wu Juntao Tang Kuanyu Yuan Chunyue Pan Guipeng Yu; supported by the National Natural Science Foundation of China(Nos.52173212,and 52103275);Hunan Provincial Natural Science Foundation for Distinguished Young Scientists(2022J10080);the Key Science and Technology Project of Changsha(KH2301015).; Advanced functionalization-decorated porous organic polymers(POPs)are emerging as a prominent research focus,spanning from their construction to applications in gas storage and separation,catalysis,energy storage,elec...; 关键词：Porous polymers Metal functionalization Adsorption CATALYSIS Active sites Functional polymers

Palladium/Xu-Phos Catalyzed Enantioselective Intramolecular Heck Reaction of Unactivated Alkenes: 《Chinese Journal of Chemistry》2024年第20期2466-2470,共5页Lujia Zhou Longling Ma Bing Xu Zhan-Ming Zhang Junliang Zhang; support of the National Key R&D Program of China(No.2021YFF0701600),NSFC(No.22031004);the Shanghai Municipal Education Commission(No.20212308);China Postdoctoral Science Foundation(No.2022M713667)and STCSM(No.23ZR1445600).; A highly enantioselective palladium-catalyzed intramolecular Heck reaction of unactivated alkenes is developed,which provides a powerful route to access a broad range of chiral 3,3-disubstituted-2,3-dihydrobenzofurans...; 关键词：PALLADIUM HECK 2 3-Dihydrobenzofuran Asymmetric catalysis Quaternary stereocenter ENANTIOSELECTIVE P ligands ALKENES

Chiral Isothiourea-Catalyzed Acylative Dynamic Kinetic Resolution of 3-Hydroxyphthalides for Enantioselective Synthesis of Phthalidyl Esters: 《Chinese Journal of Chemistry》2024年第19期2341-2345,共5页Zeyang Hao Wei Lin Zi-Qi Yuan Wei Zhang Xin Li; support from the National Natural Science Foundation of China(Grant Nos.22371219,22193011,21971120,21933008 and 22101191);National Science&Technology Fundamental Resource Investigation Program of China(No.2018FY201200);the Fundamental Research Funds for the Central Universities.W.Z.is grateful for the financial support from the program of China Scholarship Council(No.202206240054).; Comprehensive Summary Phthalides serve as core structures pervasive in a wide array of natural products and drug molecules,which display a diverse array of biological activities.We report herein a highly efficient dyn...; 关键词：Asymmetric catalysis Phthalidyl ester Dynamic kinetic resolution Chiral isothiourea ACYLATION Methodology and reactions Syntheticmethods

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